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Chemicals - Titanium Tetrachloride

Titanium Tetrachloride Titanium tetrachloride is an intermediate raw material for each of our products and is used in many fields. For example, it is used as a catalyst for manufacturing macromolecule chemical products such as polyethylene resin, as a raw material for pearl pigment, as a vapor agent for certain tools.

Uses

Titanium sponge
High purity titanium dioxide (TiO2)
Barium titanate
Polymerization catalyst (Ziegler-Natta catalyst)
Titanium tetrachloride aqueous solution

Specifications
  Chemical Composition  
GRADE TiCl4
(%)
Fe
(ppm)
V
(ppm)
Si
(ppm)
Sn
(ppm)
As
(ppm)
Sb
(ppm)
Hazen*
color
number
TLT-1 99.9min. 10max. 10max. 5max. 30max. - - 20max.
*accordance with the color indication method of American Public Health Association(APHA)

High Purity Grade -Typical Data(ppm)

Si Fe V Sb Cu As Sn Nb O C Mn Ni Cr Al P
2 1 1 0.1 1 0.1 1 1 21 8 1 1 1 1 10

Containers

Container(liter) Net Weight(kg)
2,000 3,000
5,000 7,500
6,000 10,000
12,000 19,000

Physical Properties

Molecular Weight 189.73
Boiling Point 136.4 degree C (1,013.25hPa)
Melting Point -25 degree C
Specific Gravity 1.726 (15-20 degree C)
Vapor Density 197.4 (Oxygen=16)
Vapor Pressure logP=7.64433-1947.6/T (P:mmHg,T:K)
Critical Temperature 358 degree C
Specific Heat 35.7cal/mol degree C (liquid)(13-99 degree C)
Viscosity 0.826C.P (20 degree C)
Heat of Vaporization 8.96kcal/mol (25 degree C)
Heat of Fusion 2.24kcal/mol
Heat Conductivity 0.073kcal/m.hr.degree C
Surface Tension 34.03dyn/cm (13 degree C)
Dielectric Constant 2.83 (10C), 2.79 (20 degree C)
Coefficient of Cubical Expansion 0.001086 (0-100 degree C)
Entropy 60.4±2 cal/mol.degree C (25degree C, liquid)
84.4±1 cal/mol.degree C (25 degree C, vapor)
Heat of Formation -198.5±10 kcal/mol (0 degree C, solid)
-184.3±10 kcal/mol (0 degree C, gas)


Chemical Properties

1 Reactivity against Water react with water strongly(hydrolysis) with large heat of reaction
TiCl4+H2OHCl+Ti(OH)nClx
2 Reactivity against alcohol react with alcohol to generate ester
TiCl4+4ROH+4NH3Ti(OR)4+4NH4Cl
3 Corrosion not corrosive against iron at room temperature, but corrosive at 200 degree C or more.
generate corrosive HCl when reacted with water; to eliminate moisture in vessel and pipe.

Catalysts & Chemicals Sales Dept.
TEL : +81-(0)467-87-9630 FAX : +81-(0)467-87-6954